
In 2019, EFSA published a statement on the review of the risk related to the exposure to food additive titanium dioxide (E171) performed by the French Agency for Food, Environment and Occupational Health Safety (ANSES). In its statement, EFSA highlighted that the ANSES opinion reiterated the uncertainties and data gaps previously identified by EFSA and did not present findings that invalidated the Authority’s previous conclusions on the safety of titanium dioxide.
Although barium sulfate is almost completely inert, zinc sulfide degrades upon exposure to UV light, leading to darkening of the pigment. The severity of this UV reaction is dependent on a combination of two factors; how much zinc sulfide makes up the pigments formulation, and its total accumulated UV exposure. Depending on these factors the pigment itself can vary in shade over time, ranging from pure white all the way to grey or even black. To suppress this effect, a dopant may be used, such as a small amount of cobalt salts, which would be added to the formulation. This process creates cobalt-doped zinc sulfide. The cobalt salts help to stabilize zinc sulfide so it will not have as severe a reaction to UV exposure.
Data availability statement
Resumo–Este artigo discute a descoberta de litopônio fosforescente em desenhos de aquarela do artista americano John La Farge datados de entre 1890 e 1905 e a história do litopônio na indústria de pigmento no final do século XIX e início do século XX. Apesar de ter muitas qualidades desejáveis para o uso em aquarela branca ou tintas a óleo, o desenvolvimento do litopônio como um pigmento de artistas foi prejudicado por sua tendência a se escurecer na luz solar. Sua disponibilidade para e uso por parte de artistas ainda não está clara, uma vez que os catálogos comerciais dos vendedores de tintas geralmente não eram explícitos na descrição de pigmentos brancos como algo que contém litopônio. Além disso, o litopônio pode ser confundido com o branco de chumbo durante o exame visual e sua fosforescência de curta duração pode ser facilmente perdida pelo observador desinformado. O litopônio fosforescente foi documentado em apenas um outro trabalho até hoje: uma aquarela de Van Gogh. Além da história da manufatura do litopônio, o artigo detalha o mecanismo para a sua fosforescência e sua identificação auxiliada pela espectroscopia de Raman e espectrofluorimetria.
Titanium dioxide manufacturer: Yuxing
But what is titanium dioxide, exactly? Here's what you need to know about this popular food additive — including what products it's used in and whether it's safe to consume.
Barium sulfide is produced by carbothermic reduction of barium sulfate. Zinc sulfate is obtained from a variety of zinc products, often waste, by treatment with sulfuric acid.
Food safety experts in the European Union (EU) have recently updated their safety assessment of TiO2 as a food additive. In Europe, TiO2 is referred to as E171, in accordance with European labelling requirements for food additives. The EU expert panel took into account toxicity studies of TiO2 nanoparticles, which to this point had not been considered relevant to the safety assessment of TiO2 as a food additive.
Lithopone, C.I. Pigment White 5, is a mixture of inorganic compounds, widely used as a white pigment powder. It is composed of a mixture of barium sulfate and zinc sulfide. These insoluble compounds blend well with organic compounds and confer opacity. It was made popular by the cheap production costs, greater coverage. Related white pigments include titanium dioxide, zinc oxide (zinc white), zinc sulfide, and white lead.[1]
For research published in 2022 study in the journal Food and Chemical Toxicology, scientists examined “the genotoxicity and the intracellular reactive oxygen species induction by physiologically relevant concentrations of three different TiO2 nanomaterials in Caco-2 and HT29-MTX-E12 intestinal cells, while considering the potential influence of the digestion process in the NMs’ physiochemical characteristics.” They found a “DNA-damaging effect dependent on the nanomaterial,” along with the micronucleus assay suggesting “effects on chromosomal integrity, an indicator of cancer risk, in the HT29-MTX-E12 cells, for all the tested TiO2 nanomaterials.” Researchers concluded that the results showcase “evidence of concern” regarding titanium dioxide used as a food additive.
According to data released by the China Coatings Industry Association, the total production of China's coatings industry has increased from 12.72 million tons in 2012 to 24.388 million tons in 2019, with a compound annual growth rate of 9.7%. Coatings, as an intermediate commodity, are closely related to downstream consumer markets such as the automotive industry, real estate, infrastructure, and home furnishings.
In a 2021, Chinese researchers examined the impact of E171 on lipid digestion and vitamin D3 bioaccessibility in a simulated human gastrointestinal tract model. They examined Vitamin D’s bioaccessibility, or the amount it was released in the gastrointestinal tract, becoming available for absorption, and found it “significantly decreased from 80% to 74%” with the addition of E171. In the experiment, E171 decreased lipid digestion dose-dependently. Researchers wrote: “The findings of this study enhance our understanding toward the potential impact of E171 on the nutritional attributes of foods for human digestion health.” The study was published in the Journal of Agricultural and Food Chemistry,
At present, the equipment and manufacturing process of domestic manufacturers of polyvinyl butyral are constantly getting closer to those abroad. For example, the wonderful use of polyvinyl butyral (PVB) has occurred in the printing industry and ceramic industry. Therefore, the domestic application of polyvinyl butyral (PVB) has an obvious upward trend in recent years.
For example, in the glass industry, it is because polyvinyl butyral (PVB) has good low-temperature impact strength, windability, light transmittance, light resistance, weather resistance, sound insulation, UV insulation and other properties, so that once the laminated glass is sealed together, the glass sandwich (i.e. laminated material) will appear as a whole and look like ordinary glass. For example, in the porcelain industry, polyvinyl butyral is made into a film and used for printing paper film of ceramic (or enamel) products. First, it reduces the original glue small paper Decal process, reduces the production cycle and production cost, and second, it makes its ceramic (or enamel) patterns bright in color and smooth in texture.
With the rapid development of science and technology in recent years, more and more industries have found the characteristics of polyvinyl butyral (PVB): high strength, high toughness, fatigue resistance, corrosion resistance and so on. Compared with traditional materials, polyvinyl butyral (PVB) is more and more widely used because of its larger development space and wider application fields!
Application field of polyvinyl butyral -- safety glass
The membrane made of polyvinyl butyral (PVB) is a special product used to manufacture safety glass and bulletproof glass. Safety glass is a special glass made of a layer of PVB diaphragm sandwiched between two layers of ordinary glass. It has good low-temperature impact strength, windability, light transmittance, light resistance, weather resistance, sound insulation, ultraviolet insulation and other properties. When subjected to strong external impact, PVB diaphragm can absorb impact energy, so that the glass will not break or prevent debris from hurting people. Moreover, the safety glass added with PVB diaphragm has the characteristics of high transparency, water resistance and aging resistance, and can be used in the environment of - 60 ℃. In addition, it can also be used as transparent material to replace plexiglass.
Application field of polyvinyl butyral -- ceramic film flower paper
Titanium Dioxide Raw Material Tio2 Powder
No. EFSA’s role was limited to evaluating the risks linked to titanium dioxide as a food additive. This included an assessment of relevant scientific information on TiO2, its potential toxicity, and estimates of human dietary exposure. Any legislative or regulatory decisions on the authorisations of food additives are the responsibility of the risk managers (i.e. European Commission and Member States).

